pronunciation - When to pronounce long u as "yoo" or "ooo"


Can you look at a word and see if a "u" should be pronounced as "ooo" or "yoo" by using some set of rules, or do you just have to know the correct pronunciation ahead of time?


For example:


cop[u]late "yoo"
l[u]minate "ooo"
r[u]minate "ooo"
imm[u]ne "yoo"
cons[u]me  "ooo"
comm[u]ne "yoo"


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