prepositions - Adjective + "of them"


My wife and I were discussing whether it is allowable to put an adjective in front of "of them". For instance, I could say "I want 5 cats" and "I want 5 of them". However, while it sounds perfectly normal to say "I want 5 new cats", "I want 5 new of them" doesn't roll of the tongue very smoothly.


If it is incorrect to place an adjective in front of "of them"?




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